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Automatic Tensiometer vs. Manual Tensiometer

By Hank Levi on Mon, Jan 11, 2016 @ 11:56 AM

Ever wonder what a tensiometer looked like?   

There are MANUAL TENSIOMETERS that look like this:

 manual_tensiometer-resized-600.jpg
 

PROS:

  • >Great for hands-on learning
  • >Can use virtually anywhere (does not require electricity)
  • >Easy to learn how to use
  • >Less expensive

CONS:

  • >It's manual.  You have to twist the dials by hand
  • >There is a technique to getting repeatable results
  • >Human error potential is higher
  • >Need to record results by hand

 

VIDEO DEMONSTRATION FOR MANUAL TENSIOMETER

 
 
 
 
 
 
 
 
 
 

There are AUTOMATIC TENSIOMETERS that look like this.

DY-300small.jpg
 

PROS:

  • >Easy to operate.  Press a button and walk away
  • >Run more tests quickly with high repeatability
  • >Ability to record and report data results (store historical data too)
  • >Dynamic testing features including time tests and Lamella length and more
  • >Most handle both DuNouy Ring and Wilhelmy Plate

CONS:

  • >More Expensive
  • >Some models require a computer (some don't)

VIDEO DEMONSTRATION FOR AUTOMATIC TENSIOMETER

 

To help prospective users evaluate and compare the different types of models available in the market we have prepared a reference document we call the: 

                    "Tensiometer Selection Matrix"

This matrix is not necessarily brand specific as it was designed to help those seeking to compare capabilities and prices among popular manual Tensiometer models vs. popular Automatic or "digital" Tensiometer models. 

We hope you find the Tensiometer Selection Matrix helpful in your search and evaluation of Tensiometers.

 

                        Created on 09/22/11 at 12:43:16

Click here to go to the platinum page


 

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How to test for moisture in Jet Fuel Oil using a Karl Fischer titrator

By Hank Levi on Mon, Sep 21, 2015 @ 03:15 PM


From start to finish watch this short video to see how a sample of Jet Fuel Oil is tested for water content using a karl Fischer Titrator. For this training video we use:

  1. The Aquapal III coulometric Karl Fischer Titrator (setup as a dual reagent configuration)
  2. Reagents; Anolyte is coulomat AG and the catholyte is coulomat CG
  3. A 4-place analytical balance SA-210
  4. And a disposable syringe and disposable needle

In this video you will see the steps for running a test successfully including how to:

  1. Extract your sample into the syringe
  2. How to weigh your sample and tare the balance
  3. How to inject a sample properly
  4. How to input the sample weight and obtain a final result

 

Find out more about the Aquapal III

We hope you found the video helpful and informative!  If you think a colleague could benefit from this please share it with them!  Click on the twitter button to automatically share this video!

Tweet: How to test for moisture in Jet Fuel Oil using a Karl Fischer Titrator http://bit.ly/1NJ8If4"How to test for moisture in Jet Fuel Oil using a Karl Fischer titrator"


 

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Karl Fischer Glassware and reagents 101

By Hank Levi on Mon, Sep 21, 2015 @ 01:53 PM

Many people use coulometric Karl Fischer Titrators to measure low level moisture at the part per million (PPM) level.  When it's time to start testing it's critical to have an understanding of how to:

  1. Properly identify the glassware components
  2. Assemble the glassware
  3. Identify the reagents  (anolytes and catholytes)
  4. Introduce the reagents required by the instrument and the sample being tested 

Once you have these concepts down you will have a strong working knowledge of how a Karl Fischer Titrator works and how to trouble shoot future problems.  Watch this short training video to learn more.

Find out more about the Aquapal III

If you found this information helpful please share this with your colleagues!  Just click on the tweet this button.

 Tweet: Karl Fischer glassware & reagents 101: properly identify glassware components, assemble glassware & identify reagents http://bit.ly/1Qvwv1v "Karl Fischer Glassware and reagents 101: Properly identify the glassware components, Assemble the glassware and Identify the reagents"


We hope you find the training video helpful!
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Karl Fischer Glassware and Reagents 101: How to setup.

By Hank Levi on Wed, Jun 17, 2015 @ 10:53 PM

Karl Fischer Glassware and Reagents 101:  How to setup.

 Screen_Shot_2015-06-17_at_11.16.04_PM

It seems sometimes we overlook the obvious and forget to explain some of the most basic concepts.  Sorry about that.  So we thought it might be a good idea to show how Karl Fischer Glassware is setup and how we introduce or "charge" the vessel with reagents.  We hope you enjoy this short video tutorial!

 

 Find out more about the Aquapal III

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Review of KEM's new titration line

By Hank Levi on Tue, Jun 09, 2015 @ 04:11 PM


Review of KEM's new titration line 

AT-710S_M Automatic Titrator

I don't know about you but I have to admit that I enjoy learning about new technology.  Whether it's smart phones, cars, or kitchen appliances I think it's fun to find out about how a product has changed (hopefully for the better). For the most part a lot of consumer products see a change or upgrade about once every year. This is not really the case for titrators where maybe it's only every 6 to 8 years before we see a new generation unveiled.  I guess that's why I thought maybe it would be a good idea to take a look at this new 710 series that came out in February 2015.  I haven't actually ever written a "review" before so I decided to start by comparing what I know about some of the current titrator models and identify the things that pop out with the new titration line.   Here are my observations and comments.


  

1. There are now three model levels; entry, mid-level, and flagship within each category (volumetric Karl Fischer, coulometric Karl Fischer, and automatic potentiometric titrator) 

Find more Coulometric Karl Fischer Titrator information

My comment: I like the scale of the models as it can be helpful for those with varied budgets and needs.  I like the concept that you can start with getting only the basic model at first and then later bring in the flagship model and tie them all together into one system.  It will be interesting to see how people approach these options and whether the ability to expand a system is desirable or not.
710_series_titrator_with_2_burettes

2. All of the automatic titrators now can accommodate two burette drives

 AT-710 AutomaticTitrator information

My comment: The automatic titrators come with one burette drive but being able to add a second burette drive allows an operator to run two separate titrations (titrants) without having to use an automatic piston burette.  Historically most titrator manufacturers offered only a single burette drive but it seems like this is changing.  It's kind of a big deal for those who run two different titrations and don't want to purchase an automatic piston burette.  I like this new capability.

3.  A new burette design for the automatic titrators and volumetric Karl Fischer titrators.

SmartBuretteUnit

My comment: The burettes appear they will be easier to store and swap as the titrant bottle, burette and nozzles all go together as one smaller unit.   The burettes are now "smart" burettes and can store all of the reagent information within the head of the burette.  I like this.

Learn more about Volumetric Karl Fischer Titration

4.  More Input/Output options for operators to move  and store data.  I/O options include LAN connectivity/URL, USB hubs, USB thumb drive ports, .CSV file format, .PDF file format, barcode readers, foot switches, and keyboards.710seriesUSB

My comment:  More technology is built into these units. I think it was overdue so I am glad to see it finally arrive.

AT710_w_propeller_or_magnetic_stirrer

5.  Automatic Titrators now come with a propeller stirrer by default but can swap for a magnetic stirrer instead.

My comment: I like the option to do both but I think maybe the magnetic stirrer should have been the default and the propeller as the option.

 

6.  A new Wireless/ Wired 8.4 inch color touch panel controller (MCU).

MCU_screen_view_with_multiple_units

My comment: This only comes with the mid-range and the flagship models.  The controller can sit next to the titrator or be carried around like a clipboard.  Operators can control the titrator through protective glass if necessary.  I'm not sure how many people will elect to use the wireless vs. the wired connection but it's nice to have the added capability.  Nice.

7.  Multi-titrator integration.  The wireless/wired MCU can control up to 4 different titrators simultaneously (any combination of Karl Fischer or automatic titrator) 

MCU_controller for 710 series titrators

My comment: This feature is reserved for the flagship model.  I can see this being useful for those needing to run both moisture and acid for example.  Unfortunately the mid-level model MCU cannot be upgraded to the MCU flagship model so if you think you might expand later don't go with the S model.  Your better off getting the basic "B" model and then later tying them all together from the flagship model.

 710seriesmulticontrol

8.  Free method making software.

My comment:  All of the titrators now come with a CD that allows you to create methods on your PC and then transfer methods to the titrator.  You can also pull methods off of the titrator and edit it in the PC.  The software also comes with various popular methods pre-loaded to help get methods setup quicker.  I'm not so sure how robust this software is but free is nice.

CDstoredmethods
 
 
 
 




CONCLUSION:

Well I hope this was helpful in finding out quickly what the updates are for the new 710 series.  At this point since it's so new we will have to wait to evaluate how customers feel about their user experience and get their feedback on what they liked most and what they liked least.  If you have any questions or comments you can email me at info@scientificgear.com



 

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5 ways we use liquid density information

By Hank Levi on Fri, Mar 20, 2015 @ 09:18 AM


5 ways we use liquid density information

ScreenShot2015-03-01at2.46.39PM

Some background:

Simply put density is a physical property of matter. Density is expressed as a ratio of
mass to a given volume mathematically as Density = Mass / Volume. For our industrial
purposes and earth’s known gravitational pull we will define Mass as weight.  For liquids, temperature is an important factor that can affect a liquids density.  Therefore we generally will always describe density at a given temperature for comparison purposes. In general, as liquid temperature increases, density decreases.
Knowing the density of a liquid serves numerous purposes and can provide valuable information for making decisions. Understanding what density is, what affects density, and how density affects other physical properties is important in using and translating this information into an everyday useful tool.  We can use either a hand-held density meter or benchtop density meter to evaluate a liquids density or specific gravity.


1. We live in a physical world

Earth

We live in a physical world and so it would make sense that we would want to be able
to define these physical properties around us. Having a way to define these physical
properties is helpful to those who need to use the information.
  • >How much space does it take up?
  • >How heavy is it?
  • >How much of this can we put into that?
  • >What is it?
  • >Many everyday products are packaged by volume but sold by weight.
  • >Predictive correlations can be made if you know the density.
  • >If we change some of the ingredients that make up the fluid property will it change the weight?

The neat thing about understanding liquid density is that it can answer not only the three basic questions;

  • beverage>What is the mass of the liquid?,
  • >what is the volume of the liquid?
  • >What is the density of the liquid?

But also, What is the liquid?

2. You can use a liquids density to predict 

Fluid properties are probably even more telling where predictive
correlations can be made with density measurement information. Liquid
density changes as ingredients change. A soft-drink containing more sugar for example will have a different (higher) density than a diet soft-drink. Yes,
sugar not only increases a liquid’s density but can also be inversely measured
by knowing the liquids density in a given liquid solution. Understanding these
correlations provides useful information in the production of many beverages.
 

3. Density helps us better understand how to transport fluids

Moving fluids from point A to point B. Knowing the volume and the density
helps determine the best way of transporting those fluids. The answer might
be a bigger tanker truck, or for a pipeline it may be a larger transfer pump.
Transportation

4. Density helps set petroleum prices

gaspumpPetroleum is used mostly by volume for the production of fuel, gasoline and
other energy sources. Density is used in petroleum production to give an
estimation of the gasoline or kerosene present thereby helping to determine
the price of the gasoline, for example.
 
In the oil industry quantities of crude oil are measured in metric tons.
Understanding the density allows one to calculate using API gravity the
number of barrels per metric ton –a common term of measure in the industry.
 Learn more about instruments that measure liquid density

5. Density as it relates to gravitygravity

To further explore and expand the usefulness of density measurement we focus our attention on two types of gravity.

Specific gravity

Specific gravity is another way of saying density relative to a given reference material.
In this case we usually mean relative density with respect to water. Water has a
density of 1,000 kg/m cubed at 4 degrees C. We say that water therefore has a specific
gravity of 1 (1,000/1,000). Specific gravity is the heaviness of a substance compared
to that of water. Have you ever noticed how common everyday automotive oil floats
on top of water? Automotive oil has an average density of 905 kg/m cubed at 15
wineglass
degrees C. We can calculate the specific gravity of the automotive oil by dividing 905
by 1,000 = 0.905. You can see that the number 0.905 is less than 1.0 and therefore is 
lighter than water and is why this oil floats.
Looking at specific gravity another way, for those working in the production of wine, the density of
wine increases as you add sugar but falls as the yeast eats the sugar- finished wine should
have a specific gravity somewhere between .99 and 1.01.  Who knew?

API gravity

The American Petroleum Institute (API) came up with their own gravity term referred
to as API gravity. API gravity is simply a measure of how heavy or light a petroleum
liquid is compared to water. By definition, if the petroleum’s API gravity is greater
than 10 then it is lighter than water and will float on water. If the API gravity is less
than 10 then it is heavier than water and will sink. The API gravity scale does not
have a unit of measure per say but is referred to in “degrees” with a scale from 10 to
70. This API gravity scale allows relative densities of petroleum liquids to be
compared. Why is this important? Why do we want to be able to compare petroleum
liquids? Well, the answer has to do with classifying the petroleum by quality. In the
oil industry crude oil is classified as either light, medium or heavy, according to it’s
measured API gravity! The measured API gravity will determine the class of oil and
therefore determine the value of the product.
 
crudeoil
Light crude oil has an API gravity higher than 31.1 degrees API
Medium oil has an API gravity between 22.3 degrees API and 31.1 degrees API
Heavy oil has an API gravity below 22.3 degree API
Extra Heavy oil has an API gravity less than 10 degree API

 

CONCLUSION:

It is not always easy to understand how density may apply to a given circumstance but
you can hopefully see from this brief introduction that it plays a very important role in
many or our industrial and production processes.
 
                     


Learn more about instruments that measure liquid density
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What are the best ways to measure salt and sodium in food?

By Hank Levi on Tue, Feb 17, 2015 @ 03:00 PM

Salt_and_Sodium_

What are the best ways to measure salt and sodium in food?

We have written other articles about salt testing including the Top 3 methods for measuring salt in food products and How to test for salt during food production.  But we felt this blog post was necessary to further explain how the popular methods differ during testing and why you might use one method instead of another. We also thought it was important to further explain the difference between Salt (NaCl) and Sodium (Na) and how it can impact your test results.

First thing you should know is "what are you trying to measure?"

  1. Salt (NaCl)
  2. Sodium (Na)
  3. Chloride (Cl)

The second thing is knowing your samples ingredients.

Knowing the component ingredients that make up a given food sample is very important!  If we randomly chose a method to test for salt for example without knowing the component ingredients we may discover we are way off with our answer.  Why?  Because without a clear understanding of the types of sodium and or chlorides that may be present in a sample it is possible to calculate an incorrect value either because the method of testing is incomplete for a given sample, or simple interference from other ingredients is occurring.  

Each method has it's own way of finding an answer.  Some methods look for chlorides in food, others look for sodium in food, while others measure indirectly the change in conductivity of a liquid as chlorides dissolve.  Each method has it's place and can be used effectively as long as the user knows it's capabilities and it's drawbacks. 

Understand your test objectives and choose an appropriate test method

We put together a presentation that goes into more detail on this and hope you watch it.

Watch the Full Presentation

Topics: Salt Testing
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Top 3 methods for measuring salt in food products

By Hank Levi on Thu, Jul 10, 2014 @ 04:41 PM

You may be saying to yourself, "Wait a minute! Last time you wrote about salt testing you said there were really only 2 popular methods being used.  What's going on and what is this 3rd method all about?"

Well, you are right.  Historically we have written about and discussed 2 popular methods where operators used either conductivity meters and, or, titration for testing salt in food products.  But recently we have seen a new development for testing salt levels in food products and thought it should be shared with you.  Before we do, let's review.

A quick overview on Salt:salt

When we talk about salt we need to agree on the terminology. 

Table salt or "salt" that we think about in our foods is known as sodium chloride (NaCl).  Although you cannot find NaCl on the periodic table of elements shown below, you can see both sodium (Na) and chlorine (Cl).   What's the deal with chlorine you say?  Well, chlorine under standard conditions is actually a yellow-green gas but when chlorine atoms gain one electron they become a chloride ion (Cl-).  Since an ion cannot remain in a free state all by itself it must combine with another element(s) to form a compound.  Chloride (Cl-) is therefore a by-product of the reaction between chlorine (Cl) and an electrolyte such as sodium (Na).  Hence, sodium chloride (NaCl) is known as an Ionic Compound.  There are other "related" chlorides (Ionic Compounds) but not as common and they are; calcium chloride, magnesium chloride and potassium chloride (we will save a discussion about these chlorides for another blog post).

Sodium chloride (NaCl) is naturally occurring in much of the earth's crust and can be found in places like the Great Salt Lake Basin in Utah.  A gift to this earth, nature, and our bodies!  You see, the human body needs both sodium and chloride to function properly although it's worth mentioning that there is still debate about the effects of chloride levels in the body as comparedNa with the more well known negative effects we associate with sodium (Na) and high blood pressure. 

So, when we talk about measuring and monitoring salt levels we generally are saying that we want to know how much sodium (Na) is present.  Since table salt is Na+Cl- (NaCl) then, we approach our testing for NaCl accordingly based on the ratios of each elements atomic weight and mass percent:

[NaCl = 39.3372% Na + 60.6628% Cl]

These numbers are significant because if we look for (Cl) then we can determine (Na) and or (NaCl) by doing simple math, e.g. if you can find (Cl) then you can back into (NaCl) or determine (Na).

example

 

 

 

 

 

So that's it for the salt review, lets move on to the testing methods.

 

Method #1 - A review of the Conductivity Method:

"Conductivity meters" are based on the conductivity of water and is a measure of the waters ability to pass an electrical current.  Water with more ions present will conduct more electrical current.  Seawater has more ions and is more conductive than fresh water.  In our example for testing salt (NaCl) the chloride (Cl) readily dissolves in water.  The fact that chloride (Cl) dissolves in water is key.  The more chlorides (Cl) that dissolve, the greater the number of conductive ions that will be present and therefore increase the conductivity of the water, and vice versa for lesser amounts.  The conductivity levels measured then are compared with known standards and tables like seawater.  These numbers can then be reported in micro Siemens per centimeter or other conversion scales.

The conductivity method is an indirect measurement but it is easy and fast (several seconds).  It tends to be less accurate than other methods and has some limitations with the range of measurement.

 

Method #2 - A review of the popular titration method (mohr's method):

Titration can be performed manually or by using an automatic titrator.  This popular titration method determines the chloride ion concentration.  Silver nitrate is used as the indicator and is added until all of the chloride ions are precipitated.  So, this method also measures the amount of chloride (Cl) and uses the mass percent weights to determine sodium chloride (NaCl) and or sodium (Na).

This method for measuring salt is more involved, takes a little more time (3 to 6 minutes usually), but is very accurate to the parts per million (PPM) level.  The titration method does require the use of a silver electrode/ph electrode (or combined silver electrode), silver nitrate, and someone who understands how to run the method (manual or via automatic titrator).

 

Method #3 - A new method?  Nuclear Magnetic Resonance (NMR):

Nuclear Magnetic Resonance (NMR)?  Huh?  Nuclear Magnetic Resonance (NMR) has been around since 1938 and has benefited the field of chemistry and medicine in important ways, helping researchers and chemist to identify and measure certain elements found on the periodic table.

 

The Periodic Table

 

It's only now that technology has allowed for the miniaturization of the components (magnets, etc) necessary for making a benchtop NMR device.  This greater access and ease of use with NMR technology has the potential not only for researchers and chemist but for main-stream industry to find new and useful applications for testing materials with NMR. 

So, if you can see where this is going then, YES, you guessed it.  NMR can identify and measure sodium (Na) directly with part per million (PPM) accuracy.  I will say it again, this method measures total sodium (Na) directly with part per million (PPM) accuracy.  (NaCl) and (Cl) can be determined also as we know the mass percentages for these elements.  

Although it's a new concept for the food industry this new approach for measuring sodium could prove promising because it is easy, accurate to the part per million (PPM) level, and quick too (about 30 seconds per test).  

 

                      Learn more about salt testing using (NMR)

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How to use Karl Fischer Grease

By Hank Levi on Sun, Jan 19, 2014 @ 01:57 PM

Karl Fischer GreaseCertain types of Karl Fischer vessels require the use of Karl Fischer grease. Vessels with smooth port openings need a thin layer of the grease applied to plugs, electrodes, dessicant tubes, bubbler tubes and injection port plugs to help form a snug fit.  Decreasing or limiting "ambient moisture" from getting into the vessel - otherwise known as "drift" - is the key benefit of using Karl Fischer grease.  Another benefit of Karl Fischer grease is that it also helps prevent chipping of glass on glass fittings.  Watch this short video to see how Karl Fischer Grease should be applied.

Learn more about Karl Fischer Titration
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How do Ketones & Aldehydes affect Karl Fischer moisture testing?

By Hank Levi on Mon, Sep 23, 2013 @ 04:32 PM

Measuring moisture using a karl Fischer Titrator is a common and popular choice among operators.  Karl Fischer titration provides excellent accuracy at the part-per-million (PPM) level and is widely accepted and trusted as a reliable method for measuring moisture.  Ketones and Aldehydes however are two organic compounds that can cause problems and lead to errors with measured results if they are present in a sample during testing.  The presence of these organic compounds can create an unwanted side-effect inside the titration vessel.

 ketoneWhat are the side-effects?   aldehyde

The effects are side-reactions that can either falsley increase your moisture results or falsley reduce your moisture results.  Depending on whether your dealing with ketones or aldehydes or both you will want to know how to deal with them.  

How do you solve the problem?

Once you have identified the problem you need to take stock in your equipment and the chemical reagents you are using.  The equipment setup and reagent choices you make can help you to suppress these side reactions and obtain accurate results.

Watch this short 3 minute video to learn about the preferred equipment setup and your chemical reagent choices.

 

 On a sidenote who knew that Ketones have an impact on the human body? Check out this cool review

Just thought it was interesting and wanted to share.

                           Still need help? Click here.

 

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